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Lithium molybdenum purple bronze : ウィキペディア英語版 | Lithium molybdenum purple bronze Lithium molybdenum purple bronze is a chemical compound with formula , that is, a mixed oxide of molybdenum and lithium. It can be obtained as flat crystals with a purple-red color and metallic sheen (hence the "purple bronze" name).〔〔 This compound is one of several molybdenum bronzes with general formula where A is an alkali metal or thallium Tl. It stands out among them (and also among the sub-class of "purple" molybdenum bronzes) for its peculiar electrical properties, including a marked anisotropy that makes it a "quasi-1D" conductor, and a metal-to-insulator transition as it is cooled below 30 K. ==Preparation== The compound was first obtained by Martha Greenblatt and others by a temperature gradient flux technique. In a typical preparation, a stoichometric melt of , and is maintained in a temperature gradient from 490 to 640 °C over 15 cm in vacuum over several days. Excess reagents are dissolved with a hot potassium carbonate solution releasing metallic-purple plate-like crystals, a couple mm wide and less than a mm thick.〔〔
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